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copper monosulfide : ウィキペディア英語版
copper monosulfide

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Copper sulfide is a chemical compound of copper and sulfur. It occurs in nature as the dark indigo blue mineral covellite. It is a moderate conductor of electricity.〔Wells A.F. (1962) ''Structural Inorganic Chemistry'' 3d edition Oxford University Press〕 A black colloidal precipitate of CuS is formed when hydrogen sulfide, H2S, is bubbled through solutions of Cu(II) salts. It is one of a number of binary compounds of copper and sulfur (see copper sulfide for an overview of this subject), and has attracted interest because of its potential uses in catalysis and photovoltaics.〔

==Manufacturing==
Copper sulfide can be prepared by passing hydrogen sulfide gas into a solution of copper salt.
Alternatively, it can be prepared by melting an excess of sulfur with copper(I) sulfide or by precipitation with hydrogen sulfide from a solution of anhydrous copper(II) chloride in anhydrous ethanol.
The reaction of copper with molten sulfur followed by boiling sodium hydroxide and the reaction of sodium sulfide with aqueous copper sulfate will also produce copper sulfide.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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